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61.
62.
从通识教育的时代要求和化学的学科地位出发,首先讨论了在化学类通识课程建设中引入跨学科视角的意义和可操作性。随后以通识课"化学与社会"的建设为例,系统地分享了引入跨学科视角后的课程设计理念和内容框架建设,通过课堂实施方案的论述和特色实例的分享总结了课程实施经验,并以学生访谈资料分析讨论了课程取得的效果和需要进一步完善的方向。以期为跨学科理念在化学教育教学实践中的转化和落地开拓思路、提供经验。 相似文献
63.
64.
Reliability bounds in DFRA class with known mean and variance 总被引:1,自引:0,他引:1
RELIABILITYBOUNDSINDFRACLASSWITHKNOWNMEAN AND VARIANCECHENGKAN(程侃)(InstituteofAppliedMathematics,theChineseAcademyofScience,B... 相似文献
65.
N. D. Botkin 《Applied Mathematics and Optimization》1995,32(2):195-210
A randomized algorithm for finding a hyperplane separating two finite point sets in the Euclidean space d and a randomized algorithm for solving linearly constrained general convex quadratic problems are proposed. The expected running time of the separating algorithm isO(dd! (m + n)), wherem andn are cardinalities of sets to be separated. The expected running time of the algorithm for solving quadratic problems isO(dd! s) wheres is the number of inequality constraints. These algorithms are based on the ideas of Seidel's linear programming algorithm [6]. They are closely related to algorithms of [8], [2], and [9] and belong to an abstract class of algorithms investigated in [1]. The algorithm for solving quadratic problems has some features of the one proposed in [7].This research was done when the author was supported by the Alexander von Humboldt Foundation, Germany.On leave from the Institute of Mathematics and Mechanics, Ural Department of the Russian Academy of Sciences, 620219 Ekaterinburg, S. Kovalevskaya str. 16, Russia. 相似文献
66.
Assume that the probability density function for the lifetime of a newly designed product has the form: [H(t)/Q()] exp{–H(t)/Q()}. The Exponential(), Rayleigh, WeibullW(, ) and Pareto pdf's are special cases.Q() will be assumed to have an inverse Gamma prior. Assume thatm independent products are to be tested with replacement. A Bayesian Sequential Reliability Demonstration Testing plan is used to eigher accept the product and start formal production, or reject the product for reengineering. The test criterion is the intersection of two goals, a minimal goal to begin production and a mature product goal. The exact values of various risks and the distribution of total number of failures are evaluated. Based on a result about a Poisson process, the expected stopping time for the exponential failure time is also found. Included in these risks and expected stopping times are frequentist versions, thereof, so that the results also provide frequentist answers for a class of interesting stopping rules.This research was supported by NSF grants DMS-8703620 and DMS-8923071, and forms part of the Ph.D. Thesis of the first author, the development of which was supported in part by a David Ross grant at Purdue University. The authors thank the editors and a referee for insightful comments and suggestions. 相似文献
67.
Since more than a decade, abi-scale, unified approach to strong and gravitational interactions has been proposed, that uses the geometrical methods of general relativity, and yielded results similar to strong gravity theory's. We fix our attention, in this note, on hadron structure, and show that also the strong interaction strength S, ordinarily called the (perturbative) coupling-constant square, can be evaluated within our theory, and found to decrease (increase) as the distancer decreases (increases). This yields both the confinement of the hadron constituents (for large values ofr) and their asymptotic freedom (for small values ofr inside the hadron): in qualitative agreement with the experimental evidence. In other words, our approach leads us, on a purely theoretical ground, to a dependence of S onr which had been previously found only on phenomenological and heuristic grounds. We expect the above agreement to be also quantitative, on the basis of a few checks performed in this paper, and of further work of ours on calculating meson mass spectra. 相似文献
68.
Simanenko Yu. S. Popov A. F. Prokop'eva T. M. 《Theoretical and Experimental Chemistry》2003,39(5):288-295
Among hydroxamate ions (typical nucleophiles), anomalously high nucleophilicity relative to 4-nitrophenyl diethyl phosphonate is seen in anions which have general basic catalytic sites that provide anchimeric assistance for proton transfer in the transition state. 相似文献
69.
The relative energies of one-, two-, and three-dimensional Bravais lattice Lennard-Jones particles can be calculated by lattice sums. The expression of lattice sums over a Lennard-Jones potential can be manipulated into a form that converges rapidly. A formalism capable of calculating the lattice potential at arbitrary points of a completely general lattice has been developed. This method provides an alternative way to calculate the relative energies from the surface and the interior bulk sites of many chemical systems. The method is illustrated with application to hcp and fcc Lennard-Jonesium, both for the relative binding energy and for calculating the potential along the geometric diffusion pathway between tetrahedral and octahedral interstitial sites. Diffusion from the tetrahedral site to the octahedral site experiences a barrier of 752.600 in units of 4 epsilon. The reverse pathway experiences a barrier of 1035.614 in units of 4 epsilon. 相似文献
70.
Karol Jankowski Danuta Rutkowska Andrzej Rutkowski 《Theoretical chemistry accounts》1978,48(2):119-125
It is shown that the Galerkin-Petrov method if applied in a controlled way yields reliable results for excited states of the
same symmetry classifications as the ground state. Computations are performed for the 21
S and 31
S states of He. The problem of optimizing nonlinear parameters of the basis functions by means of the GP method is discussed.
A special optimization scheme is suggested and numerically illustrated for someS states of He. 相似文献